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  • More Than You Ever Wanted to Know About Motor Oil

    More Than You Ever Wanted to Know About Motor Oil
    By Ed Hackett

    Last updated: Tuesday, 26-Feb-2002 12:19:24 MST
    Edits: v1.0 First there was 1.0. Before that there was darkness.
    v1.1 Change in description of viscosity.
    v1.2 Updated info on AMSOIL (courtesy of Morgan McArthur)


    Choosing the best motor oil is a topic that comes up frequently in
    discussions between motoheads, whether they are talking about motorcycles
    or cars. The following article is intended to help you make a choice based
    on more than the advertising hype.

    Oil companies provide data on their oils most often referred to as
    "typical inspection data". This is an average of the actual physical and a
    few common chemical properties of their oils. This information is
    available to the public through their distributors or by writing or
    calling the company directly. I have compiled a list of the most popular,
    premium oils so that a ready comparison can be made. If your favorite oil
    is not on the list get the data from the distributor and use what I have
    as a data base.

    This article is going to look at six of the most important properties of a
    motor oil readily available to the public: viscosity, viscosity index
    (VI), flash point, pour point, % sulfated ash, and % zinc.

    Viscosity is a measure of the "flowability" of an oil. More specifically,
    it is the property of an oil to develop and maintain a certain amount of
    shearing stress dependent on flow, and then to offer continued resistance
    to flow. Thicker oils generally have a higher viscosity, and thinner oils
    a lower viscosity. This is the most important property for an engine. An
    oil with too low a viscosity can shear and lose film strength at high
    temperatures. An oil with too high a viscosity may not pump to the proper
    parts at low temperatures and the film may tear at high rpm.

    The weights given on oils are arbitrary numbers assigned by the S.A.E.
    (Society of Automotive Engineers). These numbers correspond to "real"
    viscosity, as measured by several accepted techniques. These measurements
    are taken at specific temperatures. Oils that fall into a certain range
    are designated 5, 10, 20, 30, 40, 50 by the S.A.E. The W means the oil
    meets specifications for viscosity at 0 F and is therefore suitable for
    Winter use.

    Multi viscosity oils work like this: Polymers are added to a light base
    (5W, 10W, 20W), which prevent the oil from thinning as much as it warms
    up. At cold temperatures the polymers are coiled up and allow the oil to
    flow as their low numbers indicate. As the oil warms up the polymers begin
    to unwind into long chains that prevent the oil from thinning as much as
    it normally would. The result is that at 100 degrees C the oil has thinned
    only as much as the higher viscosity number indicates. Another way of
    looking at multi-vis oils is to think of a 20W-50 as a 20 weight oil that
    will not thin more than a 50 weight would when hot.

    Multi viscosity oils are one of the great improvements in oils, but they
    should be chosen wisely. Always use a multi grade with the narrowest span
    of viscosity that is appropriate for the temperatures you are going to
    encounter. In the winter base your decision on the lowest temperature you
    will encounter, in the summer, the highest temperature you expect. The
    polymers can shear and burn forming deposits that can cause ring sticking
    and other problems. 10W-40 and 5W-30 require a lot of polymers (synthetics
    excluded) to achieve that range. This has caused problems in diesel
    engines, but fewer polymers are better for all engines. The wide viscosity
    range oils, in general, are more prone to viscosity and thermal breakdown
    due to the high polymer content. It is the oil that lubricates, not the
    additives. Oils that can do their job with the fewest additives are the
    best.

    Very few manufactures recommend 10W-40 any more, and some threaten to void
    warranties if it is used. It was not included in this article for that
    reason. 20W-50 is the same 30 point spread, but because it starts with a
    heavier base it requires less viscosity index improvers (polymers) to do
    the job. AMSOIL can formulate their 10W-30 and 15W-40 with no viscosity
    index improvers but uses some in the 10W-40 and 5W-30. Mobil 1 uses no
    viscosity improvers in their 5W-30, and I assume the new 10W-30. Follow
    your manufacturer's recommendations as to which weights are appropriate
    for your vehicle.

    Viscosity Index is an empirical number indicating the rate of change in
    viscosity of an oil within a given temperature range. Higher numbers
    indicate a low change, lower numbers indicate a relatively large change.
    The higher the number the better. This is one major property of an oil
    that keeps your bearings happy. These numbers can only be compared within
    a viscosity range. It is not an indication of how well the oil resists
    thermal breakdown.

    Flash point is the temperature at which an oil gives off vapors that can
    be ignited with a flame held over the oil. The lower the flash point the
    greater tendency for the oil to suffer vaporization loss at high
    temperatures and to burn off on hot cylinder walls and pistons. The flash
    point can be an indicator of the quality of the base stock used. The
    higher the flash point the better. 400 F is the minimum to prevent
    possible high consumption. Flash point is in degrees F.

    Pour point is 5 degrees F above the point at which a chilled oil shows no
    movement at the surface for 5 seconds when inclined. This measurement is
    especially important for oils used in the winter. A borderline pumping
    temperature is given by some manufacturers. This is the temperature at
    which the oil will pump and maintain adequate oil pressure. This was not
    given by a lot of the manufacturers, but seems to be about 20 degrees F
    above the pour point. The lower the pour point the better. Pour point is
    in degrees F.

    % sulfated ash is how much solid material is left when the oil burns. A
    high ash content will tend to form more sludge and deposits in the engine.
    Low ash content also seems to promote long valve life. Look for oils with
    a low ash content.

    % zinc is the amount of zinc used as an extreme pressure, anti-wear
    additive. The zinc is only used when there is actual metal to metal
    contact in the engine. Hopefully the oil will do its job and this will
    rarely occur, but if it does, the zinc compounds react with the metal to
    prevent scuffing and wear. A level of .11% is enough to protect an
    automobile engine for the extended oil drain interval, under normal use.
    Those of you with high revving, air cooled motorcycles or turbo charged
    cars or bikes might want to look at the oils with the higher zinc content.
    More doesn't give you better protection, it gives you longer protection if
    the rate of metal to metal contact is abnormally high. High zinc content
    can lead to deposit formation and plug fouling.

    The Data:
    Listed alphabetically --- indicates the data was not available

    Brand

    VI

    Flash

    Pour

    %ash

    %zinc

    _

    20W-50

    AMSOIL (old)

    136

    482

    -38

    <.5

    ---

    AMSOIL (new)

    157

    507

    -44

    ---

    ---

    Castrol GTX

    122

    440

    -15

    .85

    .12

    Exxon High Performance

    119

    419

    -13

    .70

    .11

    Havoline Formula 3

    125

    465

    -30

    1.0

    ---

    Kendall GT-1

    129

    390

    -25

    1.0

    .16

    Pennzoil GT Perf.

    120

    460

    -10

    .9

    ---

    Quaker State Dlx.

    155

    430

    -25

    .9

    ---

    Red Line

    150

    503

    -49

    ---

    ---

    Shell Truck Guard

    130

    450

    -15

    1.0

    .15

    Spectro Golden 4

    174

    440

    -35

    ---

    .15

    Spectro Golden M.G.

    174

    440

    -35

    ---

    .13

    Unocal

    121

    432

    -11

    .74

    .12

    Valvoline All Climate

    430

    -10

    1.0

    .11

    _

    Valvoline Turbo

    140

    440

    -10

    .99

    .13

    Valvoline Race

    140

    425

    -10

    1.2

    .20

    Valvoline Synthetic

    146

    465

    -40

    <1.5

    .12

    _

    20W-40

    AMSOIL

    124

    500

    -49

    ---

    ---

    Castrol Multi-Grade

    110

    440

    -15

    .85

    .12

    Quaker State

    121

    415

    -15

    .9

    ---

    _

    15W-50

    Chevron

    204

    415

    -18

    .96

    .11

    Mobil 1

    170

    470

    -55

    ---

    ---

    Mystic JT8

    144

    420

    -20

    1.7

    .15

    Red Line

    152

    503

    -49

    ---

    ---

    _

    5W-50

    Castrol Syntec

    180

    437

    -45

    1.2

    .10

    Quaker State Synquest

    457

    -76

    ---

    ---

    _

    Pennzoil Performax

    176

    ---

    -69

    ---

    ---

    _

    5W-40

    Havoline

    170

    450

    -40

    1.4

    ---

    _

    15W-40

    AMSOIL (old)

    135

    460

    -38

    <.5

    ---

    AMSOIL (new)

    164

    462

    -49

    ---

    ---

    Castrol

    134

    415

    -15

    1.3

    .14

    Chevron Delo 400

    136

    421

    -27

    1.0

    ---

    Exxon XD3

    ---

    417

    -11

    .9

    .14

    Exxon XD3 Extra

    135

    399

    -11

    .95

    .13

    Kendall GT-1

    135

    410

    -25

    1.0

    .16

    Mystic JT8

    142

    440

    -20

    1.7

    .15

    Red Line

    149

    495

    -40

    ---

    ---

    Shell Rotella w/XLA

    146

    410

    -25

    1.0

    .13

    Valvoline All Fleet

    140

    ---

    -10

    1.0

    .15

    Valvoline Turbo

    140

    420

    -10

    .99

    .13

    _

    10W-30

    AMSOIL (old)

    142

    480

    -70

    <.5

    ---

    AMSOIL (new)

    162

    520

    -76

    ---

    ---

    Castrol GTX

    140

    415

    -33

    .85

    .12

    Chevron Supreme

    150

    401

    -26

    .96

    .11

    Exxon Superflo Hi Perf 135

    392

    -22

    .70

    .11

    _

    Exxon Superflo Supreme 133

    400

    -31

    .85

    .13

    _

    Havoline Formula 3

    139

    430

    -30

    1.0

    ---

    Kendall GT-1

    139

    390

    -25

    1.0

    .16

    Mobil 1

    160

    450

    -65

    ---

    ---

    Pennzoil PLZ Turbo

    140

    410

    -27

    1.0

    ---

    Quaker State

    156

    410

    -30

    .9

    ---

    Red Line

    139

    475

    -40

    ---

    ---

    Shell Fire and Ice

    155

    410

    -35

    .9

    .12

    Shell Super 2000

    155

    410

    -35

    1.0

    .13

    Shell Truck Guard

    155

    405

    -35

    1.0

    .15

    Spectro Golden M.G.

    175

    405

    -40

    ---

    ---

    Unocal Super

    153

    428

    -33

    .92

    .12

    Valvoline All Climate

    410

    -26

    1.0

    .11

    _

    Valvoline Turbo

    135

    410

    -26

    .99

    .13

    Valvoline Race

    130

    410

    -26

    1.2

    .20

    Valvoline Synthetic

    140

    450

    -40

    <1.5

    .12

    _

    5W-30

    AMSOIL (old)

    168

    480

    -76

    <.5

    ---

    AMSOIL (new)

    186

    464

    -76

    ---

    ---

    Castrol GTX

    156

    400

    -35

    .80

    .12

    Chevron Supreme

    202?

    354

    -46

    .96

    .11

    Chevron Supreme Synt.

    446

    -72

    1.1

    .12

    _

    Exxon Superflow HP

    148

    392

    -22

    .70

    .11

    Havoline Formula 3

    158

    420

    -40

    1.0

    ---

    Mobil 1

    165

    445

    -65

    ---

    ---

    Mystic JT8

    161

    390

    -25

    .95

    .1

    Quaker State

    165

    405

    -35

    .9

    ---

    Red Line

    151

    455

    -49

    ---

    ---

    Shell Fire and Ice

    167

    405

    -35

    .9

    .12

    Unocal

    151

    414

    -33

    .81

    .12

    Valvoline All Climate

    405

    -40

    1.0

    .11

    _

    Valvoline Turbo

    158

    405

    -40

    .99

    .13

    Valvoline Synthetic

    160

    435

    -40

    <1.5

    .12



    All of the oils above meet current SG/CD ratings and all vehicle
    manufacture's warranty requirements in the proper viscosity. All are "good
    enough", but those with the better numbers are icing on the cake.

    The synthetics offer the only truly significant differences, due to their
    superior high temperature oxidation resistance, high film strength, very
    low tendency to form deposits, stable viscosity base, and low temperature
    flow characteristics. Synthetics are superior lubricants compared to
    traditional petroleum oils. You will have to decide if their high cost is
    justified in your application.

    The extended oil drain intervals given by the vehicle manufacturers
    (typically 7500 miles) and synthetic oil companies (up to 25,000 miles)
    are for what is called normal service. Normal service is defined as the
    engine at normal operating temperature, at highway speeds, and in a dust
    free environment. Stop and go, city driving, trips of less than 10 miles,
    or extreme heat or cold puts the oil change interval into the severe
    service category, which is 3000 miles for most vehicles. Synthetics can be
    run two to three times the mileage of petroleum oils with no problems.
    They do not react to combustion and combustion by-products to the extent
    that the dead dinosaur juice does. The longer drain intervals possible
    help take the bite out of the higher cost of the synthetics. If your car
    or bike is still under warranty you will have to stick to the recommended
    drain intervals. These are set for petroleum oils and the manufacturers
    make no official allowance for the use of synthetics.

    Oil additives should not be used. The oil companies have gone to great
    lengths to develop an additive package that meets the vehicle's
    requirements. Some of these additives are synergistic, that is the effect
    of two additives together is greater than the effect of each acting
    separately. If you add anything to the oil you may upset this balance and
    prevent the oil from performing to specification.

    The numbers above are not, by any means, all there is to determining what
    makes a top quality oil. The exact base stock used, the type, quality, and
    quantity of additives used are very important. The given data combined
    with the manufacturer's claims, your personal experience, and the
    reputation of the oil among others who use it should help you make an
    informed choice.
    Mike * Seattle * 82 F'n'XJ1100 *
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